| CAS (Single) | 80-56-8 |
| FEMA | 2902 |
| EINECS | 201-291-9 |
| Synonyms |
|
| JECFA Food Flavoring | 1329 |
| JECFA Food Additive | N/A |
| DG SANTE Food Flavourings | 01.004 DL-pin-2(3)-ene |
| DG SANTE Food Contact Materials | DL-pin-2(3)-ene |
| FDA UNII | JPF3YI7O34 |
| CoE Number | 2113 |
| XlogP3-AA | N/A |
| Molecular Weight | 136.23752 |
| Molecular Formula | C10 H16 |
| Food Chemicals Codex Listed | Yes |
| Appearance | colorless to pale yellow clear liquid (est) |
| Assay | 97.00 to 100.00 sum of isomers |
| Specific Gravity | 0.85300 to 0.86100 @ 25.00 °C. |
| Lbs/Gal (est) | 7.098 to 7.164 |
| Refractive Index | 1.46300 to 1.46700 @ 20.00 °C. |
| Melting Point | -64.00 to -62.00 °C. @ 760.00 mm Hg |
| Boiling Point | 155.00 to 156.00 °C. @ 760.00 mm Hg |
| Flash Point | 90.00 °F. TCC ( 32.22 °C. ) |
| Acid Value | N/A |
| Vapor Pressure | 4.750000 mmHg @ 25.00 °C. |
| Vapor Density | N/A |
| logP (o/w) | 4.83 |
| Soluble In |
|
| Occurrence |
|
| Organoleptic Notes |
|
| Odor | herbal fresh, camphoreous, sweet, pine, earthy, woody, terpenic, cooling, herbal |
| Flavor | woody woody, pine, terpenic, camphoreous, herbal, spicy, tropical, |
Alpha-pinene is a bicyclic monoterpene and one of the most widely distributed terpenes in nature. It is commonly found in the oils of coniferous trees, particularly pine trees. The IUPAC name for alpha-pinene is (1R)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene. Its CAS number is 80-56-8, and it is recognized by FEMA with the number 2902. The molecular formula of alpha-pinene is C10H16, and it has a molecular weight of 136.24 g/mol. The compound's structure includes a bicyclic framework with a double bond, which contributes to its characteristic pine-like odor. This structural feature is crucial for its odor profile and its role in flavor and fragrance applications.
Citation hooks: FlavScents; PubChem; FEMA
Alpha-pinene is characterized by its fresh, woody, and pine-like aroma, which is both sharp and invigorating. It is often described as having a resinous and slightly balsamic undertone. The intensity of its odor is moderate to strong, making it a prominent note in formulations. While specific taste and odor thresholds are not widely documented, alpha-pinene is typically used as an impact note in both flavors and fragrances, providing a sense of freshness and natural realism.
Citation hooks: FlavScents; peer-reviewed sensory literature
Alpha-pinene is naturally occurring in the essential oils of many coniferous trees, such as pines, spruces, and firs. It is also found in rosemary, eucalyptus, and other aromatic plants. The formation of alpha-pinene in plants is primarily through the mevalonate pathway, a key biosynthetic route for terpenes. Its presence in essential oils contributes to their designation as "natural flavors" or "natural fragrances," depending on the extraction and processing methods used.
Citation hooks: FlavScents; food chemistry literature; EFSA/JECFA monographs
In flavor applications, alpha-pinene is used to impart a fresh, pine-like note, often in conjunction with other terpenes to create complex, natural profiles. It is commonly used in mint, citrus, and herbal flavors. Typical use levels in food and beverages range from 1 to 20 ppm, depending on the desired intensity and the complexity of the flavor system. Alpha-pinene is relatively stable under normal conditions but can be prone to oxidation, which may alter its sensory characteristics.
Citation hooks: FlavScents; FEMA GRAS documentation; formulation literature
Alpha-pinene is a versatile component in fragrance formulations, contributing to the freshness and naturalness of pine, woody, and herbal fragrance families. It is often used as a modifier or impact note, enhancing the top notes of a fragrance composition. Typical concentration ranges in perfumes and personal care products vary from trace amounts to 1%, depending on the desired effect. Due to its volatility, alpha-pinene primarily contributes to the top notes of a fragrance.
Citation hooks: FlavScents; IFRA; fragrance chemistry texts
In the United States, alpha-pinene is generally recognized as safe (GRAS) for use in food by FEMA. In the European Union, it is regulated under Regulation (EC) No 1334/2008 and has an assigned FL number. The United Kingdom follows similar regulations post-Brexit. In Asia, alpha-pinene is accepted in Japan and China, although specific regulations may vary. In Latin America, countries like Brazil and those in MERCOSUR have harmonized regulations for its use in flavors and fragrances. However, formulators should verify specific country regulations due to potential variability.
Citation hooks: FEMA; EFSA; national authority publications
Alpha-pinene is considered safe for use in flavors and fragrances when used within recommended levels. For oral exposure, it has a high margin of safety, with no specific ADI or MSDI established, but it is generally used at low concentrations. Dermal exposure in fragrances is typically safe, although it may cause irritation or sensitization in sensitive individuals. Inhalation exposure is generally considered safe, but occupational exposure should be monitored to prevent respiratory irritation. The risk profiles for food and fragrance applications are similar, with no significant differences noted.
Citation hooks: EFSA; FEMA; PubChem; toxicology literature
Alpha-pinene is valued for its ability to impart a fresh, natural character to both flavors and fragrances. It synergizes well with other terpenes and can enhance the perception of freshness in citrus and herbal profiles. Common pitfalls include overuse, which can lead to a harsh or resinous note, and oxidation, which can alter its sensory properties. It is often under-used in complex formulations where its subtlety can enhance overall realism.
Citation hooks: FlavScents; industry practice
The data on alpha-pinene is well-established, with extensive documentation in both flavor and fragrance applications. Industry practices are well-documented, although specific use levels may vary. Known data gaps include precise sensory thresholds and detailed regulatory nuances in certain regions. Formulators should rely on authoritative sources and industry guidelines to ensure compliance and optimal use.
Citation hooks: FlavScents
About FlavScents AInsights (Disclosure)
FlavScents AInsights integrates information from authoritative government, scientific, academic, and industry sources to provide applied, exposure-aware insight into flavor and fragrance materials. Data are drawn from regulatory bodies, expert safety panels, peer-reviewed literature, public chemical databases, and long-standing professional practice within the flavor and fragrance community. Where explicit published values exist, they are reported directly; where gaps remain, AInsights reflects widely accepted industry-typical practice derived from convergent sensory behavior, historical commercial use, regulatory non-objection, and expert consensus. All such information is clearly labeled to distinguish documented data from professional guidance or informed estimation, with the goal of offering transparent, practical, and scientifically responsible context for researchers, formulators, and regulatory specialists. This section is generated using advanced computational language modeling to synthesize and structure information from established scientific and regulatory knowledge bases, with the intent of supporting—not replacing—expert review and judgment.
Generated 2026-10-07 14:52:29 GMT (p2)
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