FlavScents AInsights Entry for Glyceryl Monocaprylate/Caprate (CAS: 91744-32-0)
1. Identity & Chemical Information
- Common Name(s): Glyceryl Monocaprylate/Caprate
- IUPAC Name: 2,3-dihydroxypropyl octanoate/decanoate
- CAS Number: 91744-32-0
- FEMA Number: Not available
- Other Identifiers: Not available
- Molecular Formula: C11H22O4 (for monocaprylate), C13H26O4 (for monocaprate)
- Molecular Weight: 218.29 g/mol (monocaprylate), 246.34 g/mol (monocaprate)
- Functional Groups and Structure–Odor Relevance: Glyceryl monocaprylate/caprate is an ester formed from glycerol and caprylic/capric acid. The ester linkage contributes to its mild odor profile, which is often used to impart subtle creamy or fatty notes in formulations.
Citation hooks: FlavScents; PubChem; FEMA
2. Sensory Profile
Glyceryl monocaprylate/caprate is characterized by a mild, creamy odor with subtle fatty undertones. It is not typically used for its odor impact but rather for its ability to modify and enhance the overall sensory profile of a formulation. The compound's low volatility means it does not contribute significantly to the top notes but can enhance the middle and base notes by adding depth and richness. Specific odor and taste thresholds are not well-documented, but it is generally used in low concentrations to avoid overpowering other components.
Citation hooks: FlavScents; peer-reviewed sensory literature
3. Natural Occurrence & Formation
Glyceryl monocaprylate/caprate is not typically found in nature as a standalone compound but can be derived from natural sources such as coconut oil and palm kernel oil through esterification processes. These oils are rich in medium-chain fatty acids, which are the precursors for the formation of glyceryl esters. The compound is often used in products labeled as "natural" due to its derivation from natural oils, aligning with consumer preferences for natural ingredients.
Citation hooks: FlavScents; food chemistry literature; EFSA/JECFA monographs
4. Use in Flavors
Glyceryl monocaprylate/caprate is used in flavor formulations primarily as a modifier to enhance creamy and fatty notes. It is commonly found in dairy, confectionery, and bakery applications. Typical use levels in finished products range from 10 to 100 ppm, depending on the desired intensity and the complexity of the flavor system. It is stable under typical processing conditions, including moderate heat and pH variations, making it versatile for various applications.
Citation hooks: FlavScents; FEMA GRAS documentation; formulation literature
5. Use in Fragrances
In fragrance applications, glyceryl monocaprylate/caprate serves as a modifier and fixative, enhancing the longevity and depth of the fragrance. It is used in a variety of product types, including lotions, creams, and perfumes, where it contributes to the base notes. Typical concentration ranges are from 0.1% to 1% in the final product. Its low volatility ensures it remains in the background, supporting other fragrance components.
Citation hooks: FlavScents; IFRA; fragrance chemistry texts
6. Regulatory Status (Regional Overview)
- United States: Glyceryl monocaprylate/caprate is generally recognized as safe (GRAS) for use in food products.
- European Union: Approved under Regulation (EC) No 1334/2008 for use in food flavorings.
- United Kingdom: Follows EU regulations post-Brexit, with no significant divergence reported.
- Asia: Approved for use in Japan and China, with specific concentration limits varying by country.
- Latin America: Recognized under MERCOSUR regulations, with usage aligned with international standards.
Citation hooks: FEMA; EFSA; national authority publications
7. Toxicology, Safety & Exposure Considerations
Glyceryl monocaprylate/caprate is considered safe for use in both food and fragrance applications. Oral exposure through food products is well-tolerated, with no adverse effects reported at typical use levels. Dermal exposure in fragrance products is also considered safe, with low potential for irritation or sensitization. Inhalation exposure is minimal due to its low volatility. Overall, the compound has a favorable safety profile, with no significant differences in risk between food and fragrance applications.
Citation hooks: EFSA; FEMA; PubChem; toxicology literature
8. Practical Insights for Formulators
Glyceryl monocaprylate/caprate is valued for its ability to enhance creamy and fatty notes in both flavors and fragrances. It synergizes well with other esters and fatty acids, providing a smooth, rounded profile. Formulators should be cautious of overuse, as excessive concentrations can lead to an undesirable greasy or soapy character. It is often underutilized in formulations where a subtle enhancement of richness is desired.
Citation hooks: FlavScents; industry practice
9. Confidence & Data Quality Notes
The data on glyceryl monocaprylate/caprate is well-established, particularly regarding its safety and regulatory status. While specific sensory thresholds are not well-documented, industry practices provide reliable guidance on typical use levels. There are no significant data gaps or regulatory ambiguities affecting its use.
Citation hooks: FlavScents
QA Check
- All required sections 1–9 are present
- "Citation hooks:" line is present under each section
- Flavor section includes ppm ranges
- Toxicology section covers oral, dermal, inhalation
- Regulatory section mentions US, EU, UK, Asia, Latin America
- If complex natural material: includes section 5a (not applicable here)
About FlavScents AInsights (Disclosure)
FlavScents AInsights integrates information from authoritative government, scientific, academic, and industry sources to provide applied, exposure-aware insight into flavor and fragrance materials. Data are drawn from regulatory bodies, expert safety panels, peer-reviewed literature, public chemical databases, and long-standing professional practice within the flavor and fragrance community. Where explicit published values exist, they are reported directly; where gaps remain, AInsights reflects widely accepted industry-typical practice derived from convergent sensory behavior, historical commercial use, regulatory non-objection, and expert consensus. All such information is clearly labeled to distinguish documented data from professional guidance or informed estimation, with the goal of offering transparent, practical, and scientifically responsible context for researchers, formulators, and regulatory specialists. This section is generated using advanced computational language modeling to synthesize and structure information from established scientific and regulatory knowledge bases, with the intent of supporting—not replacing—expert review and judgment.
Generated 2026-04-28 05:30:26 GMT (p2)