FlavScents AInsights Entry for Citronellal (CAS: 106-23-0)
1. Identity & Chemical Information
- Common Name(s): Citronellal
- IUPAC Name: 3,7-Dimethyloct-6-en-1-al
- CAS Number: 106-23-0
- FEMA Number: 2307
- Other Identifiers: FL No. 02.015
- Molecular Formula: C10H18O
- Molecular Weight: 154.25 g/mol
Citronellal is a monoterpenoid and an aldehyde, characterized by its lemon-like odor. The presence of the aldehyde group is crucial for its olfactory properties, contributing to its fresh, citrus scent. Its structure allows it to be a versatile component in both flavor and fragrance formulations.
Citation hooks: FlavScents; PubChem; FEMA
2. Sensory Profile
Citronellal is known for its distinctive lemon-like odor, often described as fresh, citrusy, and slightly floral. It is a high-impact odorant with moderate diffusion and intensity. The compound is primarily used as an impact note in formulations, providing a fresh and clean citrus character. While specific taste and odor thresholds are not widely documented, citronellal is recognized for its ability to enhance the freshness and brightness of a composition.
Citation hooks: FlavScents; peer-reviewed sensory literature
3. Natural Occurrence & Formation
Citronellal naturally occurs in the essential oils of several plants, most notably in citronella, lemongrass, and eucalyptus oils. It is biosynthesized in plants through the mevalonate pathway, a key metabolic route for the production of terpenoids. Citronellal's presence in natural sources makes it eligible for "natural flavor" or "natural fragrance" designations, depending on the extraction and processing methods used.
Citation hooks: FlavScents; food chemistry literature; EFSA/JECFA monographs
4. Use in Flavors
Citronellal is utilized in a variety of flavor categories, including citrus, mint, and herbal profiles. It serves as a functional component in flavor systems, often used to impart a fresh, lemony note. Typical use levels in finished food or beverage products range from 1 to 20 ppm, with variations depending on the desired intensity and product type. Citronellal is relatively stable under normal conditions but may degrade under high heat or acidic conditions, which should be considered during formulation.
Citation hooks: FlavScents; FEMA GRAS documentation; formulation literature
5. Use in Fragrances
In the fragrance industry, citronellal is a key component in citrus, floral, and fresh fragrance families. It acts as a modifier and impact note, contributing to the top and middle notes of a fragrance composition. Typical concentration ranges in fragrance products vary, but it is often used at levels of 0.1% to 1% depending on the formulation. Citronellal's volatility makes it an effective top note, providing an initial burst of freshness.
Citation hooks: FlavScents; IFRA; fragrance chemistry texts
6. Regulatory Status (Regional Overview)
- United States: Citronellal is generally recognized as safe (GRAS) for use in food by FEMA.
- European Union: Approved under Regulation (EC) No 1334/2008 with FL number 02.015.
- United Kingdom: Follows EU regulations post-Brexit with no significant divergence reported.
- Asia: Approved for use in Japan and China, with specific regulations varying by country.
- Latin America: Recognized under MERCOSUR regulations, with country-specific guidelines applicable.
Explicit approvals and harmonized assumptions are generally consistent across regions, though formulators should verify specific country regulations.
Citation hooks: FEMA; EFSA; national authority publications
7. Toxicology, Safety & Exposure Considerations
Citronellal is considered safe for use in food and fragrance applications when used within recommended levels. For oral exposure, it has a high margin of safety with no specific ADI established, but typical use levels are well below any concerning thresholds. Dermal exposure in fragrances is generally safe, though it may cause mild irritation or sensitization in sensitive individuals. Inhalation exposure is not typically a concern at normal usage levels, but occupational exposure should be monitored to prevent irritation.
Citation hooks: EFSA; FEMA; PubChem; toxicology literature
8. Practical Insights for Formulators
Citronellal is valued for its ability to impart a fresh, citrusy note, making it a versatile ingredient in both flavors and fragrances. It synergizes well with other citrus and floral components, enhancing the overall freshness of a composition. Formulators should be cautious of its volatility and potential for degradation under extreme conditions. It is often underutilized in complex formulations where its fresh note can provide a clean, uplifting character.
Citation hooks: FlavScents; industry practice
9. Confidence & Data Quality Notes
The data on citronellal is well-established, with comprehensive documentation available from authoritative sources. Industry practices are consistent with documented uses, though some regional regulatory nuances may require further verification. Known data gaps are minimal, primarily related to specific sensory thresholds.
Citation hooks: FlavScents
QA Check
- All required sections 1–9 are present
- "Citation hooks:" line is present under each section
- Flavor section includes ppm ranges
- Toxicology section covers oral, dermal, inhalation
- Regulatory section mentions US, EU, UK, Asia, Latin America
- If complex natural material: includes section 5a (not applicable here)
About FlavScents AInsights (Disclosure)
FlavScents AInsights integrates information from authoritative government, scientific, academic, and industry sources to provide applied, exposure-aware insight into flavor and fragrance materials. Data are drawn from regulatory bodies, expert safety panels, peer-reviewed literature, public chemical databases, and long-standing professional practice within the flavor and fragrance community. Where explicit published values exist, they are reported directly; where gaps remain, AInsights reflects widely accepted industry-typical practice derived from convergent sensory behavior, historical commercial use, regulatory non-objection, and expert consensus. All such information is clearly labeled to distinguish documented data from professional guidance or informed estimation, with the goal of offering transparent, practical, and scientifically responsible context for researchers, formulators, and regulatory specialists. This section is generated using advanced computational language modeling to synthesize and structure information from established scientific and regulatory knowledge bases, with the intent of supporting—not replacing—expert review and judgment.
Generated 2026-08-24 05:33:57 GMT (p2)